STTZ We're talking about the keyboard keys and not the buttons in the player window, right?
In the player window you need to press alt to skip 10s. If you're using the keyboard, left-arrow/right-arrow skip 10s and that cannot be modified by a modifier key.
Though, MPlayer always skips to the next keyframe and so you never get exactly the time you tell it to skip. In the file I just tried it e.g. skipped about 15 seconds on each press. If you have a file with only very few keyframes, the skip duration could be longer. There's currently no way to change that, though.
(Version rev11)