MUDFLAPPER Yeah, it's funny, Adium is the one app that has NEVER crashed on me. Not even all the beta versions.
Maybe we can help you out figure out what's causing the crashing? I'm wondering if Adium is trying to access a font that has been corrupted somehow. I'm a graphic designer and I've learned over the years that, at least with my system, most mysterious crashes are caused by bad fonts.
Let us know if we can help. In the meantime, boot from your Leopard disc, repair your startup drive, repair permissions, restart, reinstall Adium and let us know how it goes.
(Version 1.2.2)