CHARLESS The .pkg format is a read-only format. The entire archive is gzipped (or sometimes bzipped) together, so that the only way to modify it would be to unpack the entire archive, make your changes, then repack the whole thing back up. Also, the .bom format used to list the files in the package is a closed format, meaning that it cannot be edited without reverse engineering, which is liable to break if Apple decides to change the format and thus not a very good idea. So really, the best way to edit a package is to unpack its entire contents, make your changes to the files on the disk, and then use PackageMaker to make a new package.
(Version 2.6)